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Lithium Hoarding Behind Failure of Promising New Battery

New study shows how the choice of electrolyte can cause high-capacity batteries to quickly fade

March 2016
International Collaboration Studies Effects of Marine Renewable Energy Devices

Sick of your battery dying? Lightweight lithium-sulfur batteries are a promising solution that hold two times the energy of those on store shelves, but they often fade and won't hold a charge for long. Through the Joint Center for Energy Storage Research (JCESR), researchers at PNNL identified one cause behind this problem.

Electrodes Evaluations

They found that salts used in the battery liquid make a big difference. When a salt called LiTFSI is packed in the liquid, a test battery can hold most of its charge for more than 200 uses. The LiTFSI helps bind up lithium atoms and sulfur on the electrode but quickly releases them. In contrast, a similar liquid ties up the lithium and sulfur but doesn't release it. The result is an electrode that quickly degrades; the battery fades after a few dozen uses.

To determine the influence of electrolytes in lithium-sulfur batteries, the team did experiments with both LiTFSI and a similar electrolyte, called LiFSI, which has less carbon and fluoride. After continually measuring the amount of energy that the battery held and released, the team did a post-mortem analysis to study the electrodes.

They discovered that with the LiTFSI, the electrode's lithium atoms became bound up with sulfur. The result is lithium sulfide (LiSx) forming on the electrode's surface. With LiFSI, lithium sulfate (LiSOx) formed. By calculating the strength with which the compounds clung to the lithium, they found that the lithium sulfide easily broke apart to release the lithium. However, the lithium sulfate was hard to separate. The oxygen in the lithium sulfate was the culprit.

"By conducting a macroscopic compositional analysis combined with simulations, we can see which bonds are easily broken and what will happen from there," said Ji-Guang (Jason) Zhang, who led the study. "This process lets us identify the electrolytes behavior, guides us to design a better electrolyte, and improve the cycle life of lithium-sulfur batteries."

This work offers needed design principles for creating long-lasting, high-capacity batteries. For the researchers, the next step is developing an electrolyte additive that forms a protective layer on the lithium anode's surface, protecting it from the electrolyte.

This research was originally highlighted on PNNL's Physical Sciences Division webpage.

PNNL Research Team: Ruiguo Cao, Junzheng Chen, Kee Sung Han, Wu Xu, Donghai Mei, Priyanka Bhattacharya, Mark Engelhard, Jun Liu, Ji-Guang Zhang, and Karl Mueller


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