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Energy and Environment Directorate

Robert Dagle

Robert Dagle

Pacific Northwest National Laboratory
PO Box 999
Richland, WA 99352
(509) 371-6264

Biography

Robert Dagle is the Applied Catalysis II Team Leader, Senior Research Engineer, and Project Manager within the Energy Processes & Materials Division (EP&MD) of the Energy and Environment Directorate (EED) at PNNL. Mr. Dagle manages a team of staff members engaged in the development of innovative catalytic processes for the upgrading of biomass or fossil derived oxygenated intermediates (e.g., ethanol, syngas) to produce renewable or low carbon fuels and chemicals. Mr. Dagle manages multiple projects sponsored by the Department of Energy's Bioenergy Technologies Office (DOE-BETO). Current projects are aimed at converting biomass- and waste-derived ethanol to value-added fuels and chemicals, including butadiene, olefins, lubricants, high octane gasoline, and jet fuel blendstock. Mr. Dagle also manages a CRADA project sponsored by the Fuel Cell Technology Office (DOE-FCTO) aimed at developing a process for the direct conversion of methane to low-CO2 hydrogen and valuable solid carbon co-product.

Mr. Dagle has research experience with multiple catalytic processes which include steam reforming of hydrocarbons and bio-derived oxygenates, conversion of bio-derived light oxygenates to fuels or chemicals, preferential CO oxidation and selective CO methanation for PEM fuel cell applications, catalytic combustion, water-gas-shift catalysis, reactive distillation, conversion of biomass-derived aqueous products to value-added fuels and chemicals, syngas conversion technologies (e.g., synthesis of alcohols, transportation fuels, synthetic natural gas, and hydrogen), and chemical synthesis (e.g., acetic acid, olefins, alcohols). Mr. Dagle also has experience with integrating engineered catalysts within novel reactor architectures for process intensification purpose (e.g., micro/mesochannel process technology). His work has benefited clientele in both the government and private industry arena and has resulted in more than 50 journal articles and book chapters and numerous presentations. Mr. Dagle also serves on the steering committee for the Chemical Catalysis for Bioenergy (CCB) Consortium, a DOE national lab-led R&D consortium dedicated to overcoming catalysis challenges for the conversion of biomass and waste resources into fuels, chemicals, and materials. Mr. Dagle has 15 issued U.S. patents and one R&D 100 Award (2014).

Research Interests

  • Heterogeneous Catalysis
  • Chemical Process Development

Education and Credentials

  • B.S., Chemical Engineering, Washington State University, Pullman, WA 1999
  • M.S., Chemical Engineering, Washington State University, Tri-Cities, WA 2005

Affiliations and Professional Service

  • American Chemical Society (ACS)

PNNL Patents

PNNL Publications

2024

  • Dagle R.A., J.A. Lopez-Ruiz, N.W. Riedel, K.S. Kappagantula, D. Zhang, and C.A. Fernandez. 2024. Methane Pyrolysis for CO2-free H2 and Carbon Nanomaterials - CRADA 576 (Final Report). PNNL-36217. Richland, WA: Pacific Northwest National Laboratory. Methane Pyrolysis for CO2-free H2 and Carbon Nanomaterials - CRADA 576 (Final Report)
  • Satter S.S., J. Saavedra Lopez, M.L. Hubbard, Y. Jiang, R.A. Dagle, and J. Kothandaraman. 2024. "Reactive Direct Air Capture of CO2 to C-C Coupled Products using Multifunctional Materials." Green Chemistry 26, no. 14:8242-8255. PNNL-SA-192663. doi:10.1039/D4GC01244E
  • Weber R.S., M. Xu, J.A. Lopez-Ruiz, C. Jiang, J. Hu, and R.A. Dagle. 2024. "Toward Rational Design of Nickel Catalysts for Thermocatalytic Decomposition of Methane for Carbon Dioxide-Free Hydrogen and Value-Added Carbon Co-Product: A Review." ChemCatChem 16, no. 15:Art. No. e202301629. PNNL-SA-193126. doi:10.1002/cctc.202301629

2023

  • Affandy M., V. Dagle, and R.A. Dagle. 2023. Direct conversion of syngas to lower olefins precursors of jet fuel and chemicals. PNNL-34846. Richland, WA: Pacific Northwest National Laboratory. Direct conversion of syngas to lower olefins precursors of jet fuel and chemicals
  • Dagle V., G.B. Collinge, M. Rahman, A.D. Winkelman, W. Hu, J.Z. Hu, and L. Kovarik, et al. 2023. "Single-step conversion of ethanol into n-butene-rich olefins over metal catalysts supported on ZrO2-SiO2 mixed oxides." Applied Catalysis B: Environmental 331. PNNL-SA-181402. doi:10.1016/j.apcatb.2023.122707
  • Kothandaraman J., D.J. Heldebrant, J. Saavedra Lopez, and R.A. Dagle. 2023. "Mechanistic Insights to Drive Catalytic Hydrogenation of Formamide Intermediates to Methanol via Deaminative Hydrogenation." Frontiers in Energy Research 11. PNNL-SA-181662. doi:10.3389/fenrg.2023.1158499

2022

  • Dagle R.A. 2022. Methane Pyrolysis for CO2-free H2 and Carbon Nanomaterials - CRADA 576 (Abstract). PNNL-33677. Richland, WA: Pacific Northwest National Laboratory. Methane Pyrolysis for CO2-free H2 and Carbon Nanomaterials - CRADA 576 (Abstract)
  • Dagle R.A., J. Kothandaraman, and D.J. Heldebrant. 2022. Integrated Capture and Conversion of CO2 to Methanol (ICCCM) Process Technology - CRADA 449 (Final Report). PNNL-33642. Richland, WA: Pacific Northwest National Laboratory. Integrated Capture and Conversion of CO2 to Methanol (ICCCM) Process Technology - CRADA 449 (Final Report)
  • Dagle V., and R.A. Dagle. 2022. Conversion of syngas into light olefins in one step for process-intensified production of sustainable aviation fuels. PNNL-33370. Richland, WA: Pacific Northwest National Laboratory. Conversion of syngas into light olefins in one step for process-intensified production of sustainable aviation fuels
  • Jiang C., I. Wang, X. Bai, S. Balyan, B. Robinson, J. Hu, and W. Li, et al. 2022. "Methane catalytic pyrolysis by microwave and thermal heating over carbon nanotube-supported catalysts: productivity, kinetics, and energy efficiency." Industrial and Engineering Chemistry Research 61, no. 15:5080-5092. PNNL-SA-171877. doi:10.1021/acs.iecr.1c05082
  • Winkelman A.D., V. Dagle, T.L. Lemmon, L. Kovarik, Y. Wang, and R.A. Dagle. 2022. "Effect of Alkali Metal Addition on Catalytic Performance of Ag/ZrO2/SBA-16 Catalyst for Single-Step Conversion of Ethanol to Butadiene." Catalysis Science & Technology 13, no. 4:975-983. PNNL-SA-180968. doi:10.1039/d2cy01722a

2021

  • Lin F., V. Dagle, A.D. Winkelman, M.H. Engelhard, L. Kovarik, Y. Wang, and Y. Wang, et al. 2021. "Understanding the Deactivation of Ag-ZrO2/SiO2 Catalysts for the Single-Step Conversion of Ethanol to Butenes." ChemCatChem 13, no. 3:999-1008. PNNL-SA-158105. doi:10.1002/cctc.202001488
  • Maddi B., S.D. Davidson, H.M. Job, R.A. Dagle, M.F. Guo, M.J. Gray, and K. Kallupalayam Ramasamy. 2021. "Production of Gaseous Olefins from Syngas over a Cobalt-HZSM-5 Catalyst." Catalysis Letters 151, no. 2:526-537. PNNL-SA-134786. doi:10.1007/s10562-020-03324-7
  • Wang I., R.A. Dagle, T.S. Khan, J.A. Lopez-Ruiz, L. Kovarik, Y. Jiang, and M. Xu, et al. 2021. "Catalytic decomposition of methane into hydrogen and high-value carbons: combined experimental and DFT computational study." Catalysis Science & Technology 11, no. 14:4911-4921. PNNL-SA-163856. doi:10.1039/D1CY00287B
  • Wildfire C., V. Abdel-Sayed, D. Shekhawat, R.A. Dagle, S.D. Davidson, and J. Hu. 2021. "Microwave-assisted ammonia synthesis over Ru/MgO catalysts at ambient pressure." Catalysis Today 365. PNNL-SA-153688. doi:10.1016/j.cattod.2020.06.013
  • Xu M., J.A. Lopez-Ruiz, L. Kovarik, M.E. Bowden, S.D. Davidson, R.S. Weber, and I. Wang, et al. 2021. "Structure sensitivity and its effect on methane turnover and carbon co-product selectivity in thermocatalytic decomposition of methane over supported Ni catalysts." Applied Catalysis A: General 611. PNNL-SA-158733. doi:10.1016/j.apcata.2020.117967

2020

  • Akhade S.A., A.D. Winkelman, V. Dagle, L. Kovarik, S.F. Yuk, M. Lee, and J. Zhang, et al. 2020. "Influence of Ag metal dispersion on the thermal conversion of ethanol to butadiene over Ag-ZrO2/SiO2 catalysts." Journal of Catalysis 386. PNNL-SA-143386. doi:10.1016/j.jcat.2020.03.030
  • Dagle R.A., A.D. Winkelman, K. Kallupalayam Ramasamy, V. Dagle, and R.S. Weber. 2020. "Ethanol as a renewable building block for fuels and chemicals." Industrial and Engineering Chemistry Research 59, no. 11:4843-4853. PNNL-SA-148314. doi:10.1021/acs.iecr.9b05729
  • Dagle R.A., V. Dagle, and J. Saavedra Lopez. 2020. Improved Value of the Gasoline and Fuel Oil Co-Product Fractions Generated by the PNNL/LanzaTech Alcohol-to-Jet Process - CRADA 394 (Final Report). PNNL-30831. Richland, WA: Pacific Northwest National Laboratory. Improved Value of the Gasoline and Fuel Oil Co-Product Fractions Generated by the PNNL/LanzaTech Alcohol-to-Jet Process - CRADA 394 (Final Report)
  • Dagle R.A., V. Dagle, M.D. Bearden, J.D. Holladay, T.R. Krause, and S. Ahmed. 2020. "Hydrogen and Solid Carbon Products from Natural Gas: A Review of Process Requirements, Current Technologies, Market Analysis, and Preliminary Techno Economic Assessment." In Direct Natural Gas Conversion to Value-Added Chemicals, edited by J. Hu and D Shekhawat. Oxfordshire:Taylor & Francis Group. PNNL-SA-134166. doi:10.1201/9780429022852
  • Dagle V., A.D. Winkelman, N.R. Jaegers, J. Saavedra Lopez, J.Z. Hu, M.H. Engelhard, and S. Habas, et al. 2020. "Single-Step Conversion of Ethanol to n-Butene over Ag-ZrO2/SiO2 Catalysts." ACS Catalysis 10, no. 18:10602-10613. PNNL-SA-151691. doi:10.1021/acscatal.0c02235
  • Hu J., C. Wildfire, A. Stiegman, R.A. Dagle, D. Shekhawat, V. Abdel-Sayed, and X. Bai, et al. 2020. "Microwave-driven heterogeneous catalysis for activation of dinitrogen to ammonia under atmospheric pressure." Chemical Engineering Journal 397. PNNL-SA-143389. doi:10.1016/j.cej.2020.125388

2019

  • Bharadwaj V.S., B. Pecha, L. Bu, V. Dagle, R.A. Dagle, and P. Ciesielski. 2019. "Multi-scale simulation of reaction, transport and deactivation in SBA-16 supported catalyst for the conversion of ethanol to butadiene." Catalysis Today 338. PNNL-SA-139387. doi:10.1016/j.cattod.2019.05.042
  • Dagle V., R.A. Dagle, L. Kovarik, F. Baddour, S. Habas, and R.T. Elander. 2019. "Single-step Conversion of Methyl Ethyl Ketone to Olefins over ZnxZryOz Catalysts in Water." ChemCatChem 11, no. 15:3393-3400. PNNL-SA-140968. doi:10.1002/cctc.201900292
  • Saavedra Lopez J., R.A. Dagle, V. Dagle, C.D. Smith, and K.O. Albrecht. 2019. "Oligomerization of ethanol-derived propene and isobutene mixtures to transportation fuels: catalyst and process considerations." Catalysis Science & Technology 9, no. 5:1117-1131. PNNL-SA-135575. doi:10.1039/C8CY02297F
  • Saavedra Lopez J., V. Dagle, C.A. Deshmane, L. Kovarik, R.S. Wegeng, and R.A. Dagle. 2019. "Methane and Ethane Steam Reforming over MgAl2O4-Supported Rh and Ir Catalysts: Catalytic Implications for Natural Gas Reforming Application." Catalysts 9, no. 10:Article No. 801. PNNL-SA-146376. doi:10.3390/catal9100801

2018

  • Dagle V., M.D. Flake, T.L. Lemmon, J. Saavedra Lopez, L. Kovarik, and R.A. Dagle. 2018. "Effect of the SiO2 Support on the Catalytic Performance of Ag/ZrO2/SiO2 Catalysts for the Single-Bed Production of Butadiene from Ethanol." Applied Catalysis B: Environmental 236. PNNL-SA-128543. doi:10.1016/j.apcatb.2018.05.055
  • Kothandaraman J., R.A. Dagle, V. Dagle, S.D. Davidson, E.D. Walter, S.D. Burton, and D.W. Hoyt, et al. 2018. "Condensed-Phase Low Temperature Heterogeneous Hydrogenation of CO2 to Methanol." Catalysis Science & Technology 8, no. 19:5098-5103. PNNL-SA-133245. doi:10.1039/C8CY00997J

2017

  • Davidson S.D., K.A. Spies, D. Mei, L. Kovarik, I.V. Kutnyakov, X.S. Li, and V. Dagle, et al. 2017. "Steam Reforming of Acetic Acid over Co-supported Catalysts: Coupling Ketonization for Greater Stability." ACS Sustainable Chemistry & Engineering 5, no. 10:9136-9149. PNNL-SA-125545. doi:10.1021/acssuschemeng.7b02052
  • Spies K.A., J.E. Rainbolt, X.S. Li, B. Braunberger, L. Li, D.L. King, and R.A. Dagle. 2017. "Warm Cleanup of Coal-Derived Syngas: Multicontaminant Removal Process Demonstration." Energy and Fuels 31, no. 3:2448-2456. PNNL-SA-120510. doi:10.1021/acs.energyfuels.6b02568

2016

  • Lebarbier V.M., C.D. Smith, M.D. Flake, K.O. Albrecht, M.J. Gray, K.K. Ramasamy, and R.A. Dagle. 2016. "Integrated Process for the Catalytic Conversion of Biomass-Derived Syngas into Transportation Fuels." Green Chemistry 18, no. 7:1880-1891. PNNL-SA-113248. doi:10.1039/c5gc02298c
  • Lebarbier V.M., R.A. Dagle, L. Kovarik, A. Genc, Y. Wang, M.E. Bowden, and H. Wan, et al. 2016. "Steam Reforming of Hydrocarbons from Biomass-Derived Syngas over MgAl2O4-Supported Transition Metals and Bimetallic IrNi Catalysts." Applied Catalysis B: Environmental 184. PNNL-24262. doi:10.1016/j.apcatb.2015.11.022
  • Smith C.D., V.M. Lebarbier, M.D. Flake, K.K. Ramasamy, L. Kovarik, M.E. Bowden, and T. Onfroy, et al. 2016. "Conversion of Syngas-Derived C2+ Mixed Oxygenates to C3-C5 Olefins over ZnxZryOz Mixed Oxides Catalysts." Catalysis Today 6, no. 7:2325-2316. PNNL-SA-111860. doi:10.1039/C5CY01261A
  • Tan E., L.J. Snowden-Swan, M. Talmadge, A. Dutta, S.B. Jones, K. Kallupalayam Ramasamy, and M.J. Gray, et al. 2016. "Comparative Techno-economic Analysis and Process Design for Indirect Liquefaction Pathways to Distillate-range Fuels via Biomass-derived Oxygenated Intermediates Upgrading." Biofuels, Bioproducts & Biorefining 11, no. 1:41-66. PNNL-SA-120207. doi:10.1002/bbb.1710
  • Xing R., V.M. Lebarbier, M.D. Flake, L. Kovarik, K.O. Albrecht, C.A. Deshmane, and R.A. Dagle. 2016. "Steam Reforming of Fast Pyrolysis-Derived Aqueous Phase Oxygenates over Co, Ni, and Rh Metals Supported on MgAl2O4." Catalysis Today 269. PNNL-SA-111967. doi:10.1016/j.cattod.2015.11.046

2015

  • Mei D., V.M. Lebarbier, R. Xing, K.O. Albrecht, and R.A. Dagle. 2015. "Steam Reforming of Ethylene Glycol over MgAl2O4 Supported Rh, Ni, and Co Catalysts." ACS Catalysis 6, no. 1:315-325. PNNL-SA-112396. doi:10.1021/acscatal.5b01666
  • Zheng F., R. Diver, D.D. Caldwell, B.G. Fritz, R.J. Cameron, P.H. Humble, and W.E. TeGrotenhuis, et al. 2015. "Integrated solar thermochemical reaction system for steam methane reforming." Energy Procedia 69. PNNL-SA-104155. doi:10.1016/j.egypro.2015.03.204

2014

  • Dagle R.A., J.A. Lizarazo Adarme, V.M. Lebarbier, M.J. Gray, J.F. White, D.L. King, and D.R. Palo. 2014. "Syngas Conversion to Gasoline-Range Hydrocarbons over Pd/ZnO/Al2O3 and ZSM-5 Composite Catalyst System." Fuel Processing Technology 123. PNNL-SA-86935. doi:10.1016/j.fuproc.2014.01.041
  • Kwak J., R.A. Dagle, G.C. Tustin, J.R. Zoeller, L.F. Allard, and Y. Wang. 2014. "Molecular Active Sites in Heterogeneous Ir-La/C Catalyzed Carbonylation of Methanol to Acetates." The Journal of Physical Chemistry Letters 5, no. 3:566-572. PNWD-SA-9799. doi:10.1021/jz402728e
  • Lebarbier Dagel V.M., R.A. Dagle, J. Li, C.A. Deshmane, C.E. Taylor, X. Bao, and Y. Wang. 2014. "Direct Conversion of Syngas-to-Hydrocarbons over Higher Alcohols Synthesis Catalysts Mixed with HZSM-5." Industrial and Engineering Chemistry Research 53, no. 36:13928-13934. PNNL-SA-103407. doi:10.1021/ie502425d
  • Lebarbier V.M., R.A. Dagle, L. Kovarik, K.O. Albrecht, X.S. Li, L. Li, and C.E. Taylor, et al. 2014. "Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, and CO2 Capture." Applied Catalysis. B, Environmental 144. PNNL-SA-90830. doi:10.1016/j.apcatb.2013.06.034
  • Mei D., V.A. Glezakou, V.M. Lebarbier, L. Kovarik, H. Wan, K.O. Albrecht, and M.A. Gerber, et al. 2014. "Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Theoretical Study." Journal of Catalysis 316. PNNL-SA-99099. doi:10.1016/j.jcat.2014.04.021

2013

  • Dagle R.A., J. Hu, S.B. Jones, W.A. Wilcox, J.G. Frye, J.F. White, and J. Jiang, et al. 2013. "Carbon Dioxide Conversion to Valuable Chemical Products over Composite Catalytic Systems." Journal of Energy Chemistry 22, no. 3:368-374. PNNL-SA-92509. doi:10.1016/S2095-4956(13)60047-9
  • Dagle R.A., V.M. Lebarbier, K.O. Albrecht, J. Li, C.E. Taylor, X. Bao, and Y. Wang. 2013. "Syngas Conversion to Hydrocarbon Fuels through Mixed Alcohol Intermediates." In 23rd North American Catalysis Society Meeting, June 2-7, 2013, Louisville, Kentucky, Paper No. P-M-BRC-147. N/A:North American Catalysis Society. PNNL-SA-92427.
  • Howard C.J., R.A. Dagle, V.M. Lebarbier, J.E. Rainbolt, L. Li, and D.L. King. 2013. "Progress toward Biomass and Coal-Derived Syngas Warm Cleanup: Proof-of-Concept Process Demonstration of Multicontaminant Removal for Biomass Application." Industrial and Engineering Chemistry Research 52, no. 24:8125-8138. PNNL-SA-92772. doi:10.1021/ie4004927
  • Mei D., V.M. Lebarbier, R.J. Rousseau, V.A. Glezakou, K.O. Albrecht, L. Kovarik, and M.D. Flake, et al. 2013. "Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts." ACS Catalysis 3, no. 6:1133-1143. PNNL-SA-93222. doi:10.1021/cs4000427

2012

  • Lebarbier V.M., R.A. Dagle, L. Kovarik, J.A. Lizarazo Adarme, D.L. King, and D.R. Palo. 2012. "Synthesis of Methanol and Dimethyl Ether from Syngas over Pd/ZnO/Al2O3 Catalysts." Catalysis Science & Technology 2, no. 10:2116-2127. PNNL-SA-85225. doi:10.1039/C2CY20315D
  • Zhu Y., S.B. Jones, M.J. Biddy, R.A. Dagle, and D.R. Palo. 2012. "Single-Step Syngas-to-Distillates (S2D) Process Based on Biomass-Derived Syngas - A Techno-Economic Analysis." Bioresource Technology 117. PNNL-SA-83001. doi:10.1016/j.biortech.2012.04.027

2011

  • Dagle R.A., A.M. Karim, G. Li, Y. Su, and D.L. King. 2011. "Syngas Conditioning." In Fuel Cells: Technologies for Fuel Processing, edited by D Shekhawat, JJ Spivey and DA Berry. 361-408. Amsterdam:Elsevier. PNNL-SA-72319.

2010

  • Lebarbier V., R.A. Dagle, A.K. Datye, and Y. Wang. 2010. "The effect of PdZn particle size on reverse-water-gas-shift reaction." Applied Catalysis. A, General 379, no. 1-2:3-6. PNNL-SA-68800.
  • Li L., C.J. Howard, D.L. King, M.A. Gerber, R.A. Dagle, and D.J. Stevens. 2010. "Regeneration of Sulfur Deactivated Ni-based Biomass Syngas Cleaning Catalysts." Industrial and Engineering Chemistry Research 49, no. 20:10144-10148. PNNL-SA-68645. doi:10.1021/ie101032x

2008

  • Dagle R.A., A. Platon, A.K. Datye, J.M. Vohs, Y. Wang, and D.R. Palo. 2008. "PdZnAl Catalysts for the Reactions of Water-Gas-Shift, Methanol Steam Reforming, and Reverse-Water-Gas-Shift." Applied Catalysis. A, General 342, no. 1-2:63-68. PNNL-SA-58369. doi:10.1016/j.apcata.2008.03.005
  • Dagle R.A., and R.S. Wegeng. 2008. "Microchannel CO Methanation Reactors for Martian and Lunar ISRU." In Proceedigns of the 6th International Energy Conversion Engineering Conference (IECEC 2008), 2, 1123-1130. Reston, Virginia:American Institute of Aeronautics and Astronautics. PNNL-SA-61233.
  • Hu J., R.A. Dagle, B.R. Johnson, H.W. Kreuzer, D.J. Gaspar, B.Q. Roberts, and M.L. Alexander. 2008. "Development of a Micropyrolyzer for Enhanced Isotope Ratio Measurement." Industrial and Engineering Chemistry Research 47, no. 22:8625-8630. PNNL-SA-60695. doi:10.1021/ie8009236
  • Lebarbier V.M., R.A. Dagle, T. Conant, J.M. Vohs, A.K. Datye, and Y. Wang. 2008. "CO/FTIR Spectroscopic Characterization of Pd/ZnO/Al2O3 Catalysts for Methanol Steam Reforming." Catalysis Letters 122, no. 3-4:223-227. PNNL-SA-58426. doi:10.1007/s10562-008-9407-7

2007

  • Dagle R.A., Y. Chin, and Y. Wang. 2007. "The Effects of PdZn Crystallite Size on Methanol Steam Reforming." Topics in Catalysis 46, no. 3-4:358-362. PNNL-SA-52371. doi:10.1007/s11244-007-9009-4
  • Dagle R.A., Y. Wang, G. Xia, J.J. Strohm, J.D. Holladay, and D.R. Palo. 2007. "Selective CO Methanation Catalysts for Fuel Processing Applications." Applied Catalysis. A, General 326, no. 2:213-218. PNWD-SA-7415.
  • Johnson B.R., N.L. Canfield, D.N. Tran, R.A. Dagle, X.S. Li, J.D. Holladay, and Y. Wang. 2007. "Engineered SMR catalysts based on hydrothermally stable, porous, ceramic supports for microchannel reactors." Catalysis Today 120, no. 1:54-62. PNNL-SA-53034.
  • Palo D.R., R.A. Dagle, and J.D. Holladay. 2007. "Methanol Steam Reforming for Hydrogen Production." Chemical Reviews 107, no. 10:3992-4021. PNNL-SA-53246. doi:10.1021/cr050198b
  • Palo D.R., V.S. Stenkamp, J.D. Holladay, P.H. Humble, R.A. Dagle, and K.P. Brooks. 2007. "Non-Reactor Micro-Component Development." In Micro-Instrumentation for High Throughput Experimentation and Process Intensification, edited by MV Koch, KM VandenBussche, R Chrisman. 131-180. Weinheim:Wiley-VHC. PNNL-SA-47051.

2006

  • Palo D.R., V.S. Stenkamp, R.A. Dagle, and G.N. Jovanovic. 2006. "Industrial Applications of Microchannel Process Technology in the United States." In Micro Process Engineering, edited by N Kockmann. 387-414. Germany:Wiley-VCH. PNNL-SA-46104.

2005

  • Holladay J.D., E.O. Jones, R.A. Dagle, G. Xia, C. Cao, and Y. Wang. 2005. "Miniaturization of a Hydrogen Plant." In Microreactor Technology and Process Intensification, ACS Symposium Series, edited by Yong Wang and Jamelyn D. Holladay. 162-178. Washington, District Of Columbia:American Chemical Society. PNNL-SA-42455.
  • Palo D.R., J.D. Holladay, R.A. Dagle, and Y. Chin. 2005. "Integrated Methanol Fuel Processors for Portable Fuel Cell Systems." In Microreactor Technology and Process Intensification, ACS Symposium Series, edited by Yong Wang and Jamelyn D. Holladay. 209-223. Washington, District Of Columbia:American Chemical Society. PNNL-SA-42194.
  • Xia G., J.D. Holladay, R.A. Dagle, E.O. Jones, and Y. Wang. 2005. "Development of Highly Active Pd-ZnO/Al2O3 Catalysts for Microscale Fuel Processor Applications." Chemical Engineering and Technology 28, no. 4:515-519. PNWD-SA-6815.

2004

  • Holladay J.D., E.O. Jones, R.A. Dagle, G. Xia, C. Cao, and Y. Wang. 2004. "High Efficiency and Low Carbon Monoxide Micro-scale Methanol Processors." Journal of Power Sources 131, no. 1-2:69-72. PNWD-SA-6285.

2003

  • Chin Y., Y. Wang, R.A. Dagle, and X.S. Li. 2003. "Methanol steam reforming over Pd/ZnO: catalyst preparation and pretreatment studies." Fuel Processing Technology 83, no. 1-3:193-201. PNNL-SA-36816.
  • Holladay J.D., E.O. Jones, D.R. Palo, M.R. Phelps, Y. Chin, R.A. Dagle, and J. Hu, et al. 2003. "Miniature Fuel Processors for Portable Fuel Cell Power Supplies." In Solid State Ionics--2002 : Symposium held December 2-5, 2002, Boston, Massachusetts, U.S.A. / Materials Research Society Symposium Proceedings, edited by Philippe Knauth and Hubert A. Gasteiger, 756, 429-434. Warrendale, Pennsylvania:Materials Research Society. PNWD-SA-5862.
  • Hu J., Y. Wang, D.P. Vanderwiel, Y. Chin, D.R. Palo, R.T. Rozmiarek, and R.A. Dagle, et al. 2003. "Fuel Processing for Portable Power Applications." Chemical Engineering Journal 93, no. 1:55-60. PNWD-SA-5432.
  • Palo D.R., E.G. Baker, Y. Chin, J.D. Holladay, and R.A. Dagle. 2003. "Fuel Processor Development for a Soldier-Portable Power System." In AIChE 2003 Spring National Meeting, 2nd Topical Conference on Fuel Cell Technology, 143-147. New York, New York:AIChE. PNWD-SA-5863.

2002

  • Chin Y., R.A. Dagle, J. Hu, A. Dohnalkova, and Y. Wang. 2002. "Steam Reforming of Methanol Over Highly Active Pd/ZnO Catalyst." Catalysis Today 77 (1-2), no. DEC 1 2002:79-88. PNWD-SA-5948.
  • Chin Y., R.A. Dagle, J. Hu, A. Dohnalkova, and Y. Wang. 2002. "Steam Reforming of Methanol over Highly Active Pd/ZnO Catalyst." Catalysis Today 77, no. 1-2:79-88. PNWD-SA-5685.
  • Hu J., Y. Wang, Y. Chin, D.R. Palo, J.D. Holladay, R.T. Rozmiarek, and R.A. Dagle, et al. 2002. "Catalytic Hydrogen Production for Small Portable Power Applications." In ACS Annual Meeting, Fuel Chemistry Division Preprints, Boston, Massachusetts, 47, 725-726. Washington Dc:American Chemical Society. PNWD-SA-5662.
  • Palo D.R., J.D. Holladay, R.T. Rozmiarek, C.E. Guzman-Leong, Y. Wang, J. Hu, and Y. Chin, et al. 2002. "Development of a Soldier-Portable Fuel Cell Power System, Part I: A Bread-Board Methanol Fuel Processor." Journal of Power Sources 108, no. 1-2:28-34. PNWD-SA-5518.
  • Palo D.R., J.D. Holladay, R.T. Rozmiarek, C.E. Guzman-Leong, Y. Wang, J. Hu, and Y. Chin, et al. 2002. "Fuel Processor Development for a Soldier-Portable Fuel Cell System." In Microreaction Technology, IMRET 5: Proceedings of the Fifth International Conference on Microreaction Technology, edited by M. Matlosz, W. Ehrfeld, J.P. Baselt, 359-367. Berlin, :Springer-Verlag. PNWD-SA-5297.

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