Wu Xu
Pacific Northwest National Laboratory
PO Box 999
Richland, WA 99352
(509) 375-6934
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Biography
Dr. Wu Xu is currently a Chief Scientist in the Battery Materials and Systems Group in the Energy Processes and Materials Division at PNNL. He has 30 years’ knowledge and experience in the development of novel electrolytes and electrode materials for various energy storage systems including lithium ion batteries, lithium metal batteries, lithium-air batteries, redox flow batteries, electrochemical capacitors and electrochromic display devices. He also has expertise in the synthesis of novel lithium salts, organic solvents, ionic liquids and polymer electrolytes, and the characterization and evaluation of structures, morphologies and electrochemical performances. Before joining PNNL in April 2008, he was a Senior Scientist in the Electrolyte Business Group of Ferro Corporation in Cleveland, Ohio for four years. Prior to that, he was a Faculty Research Associate/Postdoctoral Fellow in the Department of Chemistry and Biochemistry at Arizona State University. Dr. Xu has over 200 papers published in peer reviewed professional journals and books, including 2 in Science, 10 in Nature sister journals, 1 book and 7 book chapters. He also holds 33 U.S. patents granted (19 from PNNL) with other 11 patents pending (at PNNL).
Research Interests
- Dr. Xu's research interests include the development of materials (electrolytes and electrodes), the investigation of electrode/electrolyte interphases and the integration of batteries, for various energy storage systems including lithium batteries, organic redox flow batteries and supercapacitors.
Education and Credentials
- Ph.D., Chemistry, National University of Singapore, Singapore, February 2000
- M. Eng., Fine Chemicals, East China University of Science and Technology, China, July 1989
- B. Eng., Fine Chemicals, Tianjin University, China, July 1986
Affiliations and Professional Service
- Journal of Power Sources Advances – Editorial Board
- Beyond Lithium-Ion Symposium Organization Committee
- Materials Research Society
- The Electrochemical Society
Awards and Recognitions
- 2020 Highly Cited Researcher by Clarivate Analytics, November 2020
- Distinguished Inventor of Battelle Award, September 2020
- PNNL 2019 Pathway to Excellence Patent Award, September 2020
- PNNL 2018 Pathway to Excellence Patent Award, May 2019
- PNNL Energy and Environment Directorate Outstanding Performance Award, March 2019
- PNNL Energy and Environment Directorate 2018 Of-The-Year Project Team Award, December 2018
- 2018 Highly Cited Researcher by Clarivate Analytics, November 2018
- PNNL Energy and Environment Directorate 2017 Of-The-Year Publication Award, December 2017
- PNNL Physical and Computational Sciences Directorate Outstanding Performance Award, November 2017
- PNNL Energy and Environment Directorate Outstanding Performance Award, October 2017
- PNNL 2016 Pathway to Excellence Patent Award, April 2017.
- PNNL 2015 Pathway to Excellence Patent Award, March 2016.
- PNNL 2014 Pathway to Excellence Patent Award, May 2015.
- PNNL 2014 Pathway to Excellence Key Contributor – Intellectual Property Award, May 2015.
- Battelle Recognition Award of Inventor-of-the-Year of Pacific Northwest National Laboratory, May 2014.
- PNNL 2013 Inventor-of-the-Year Award, April 2014.
- PNNL 2013 Pathway to Excellence Patent Award, April 2014.
- PNNL 2013 Pathway to Excellence Key Contributor – Intellectual Property Award, April 2014.
- PNNL Energy and Environment Directorate 2013 Of-the-Year Publication Award, December 2013.
- PNNL 2012 Pathway to Excellence Microscopy Today 2012 Innovation Award.
- Microscopy Today 2012 Renovation Award.
- 2012 R&D 100 Award.
- PNNL Energy and Environment Directorate 2012 Of-the-Year Award – 2012 EED CSM Award Nomination, December 2012.
- PNNL Energy and Environment Directorate Outstanding Performance Award, 2012, 2010, 2009, 2008.
- Discovering Excellence Award “2007 Innovator of the Year” by Arizona Technology Enterprises and Arizona State University, United States, April 2007.
- Natural Science Prize of Chinese Academy of Sciences, China, 1995.
- Excellent Supervisors Award of Chengdu University of Science and Technology, China, 1991.
PNNL Patents
- U.S. Patent No. 12,087,910, September 10, 2024, "ELECTROLYTES FOR LITHIUM BATTERIES WITH CARBON AND/OR SILICON ANODES (iEdison No. 0685901-20-0027)".
- U.S. Patent No. 11,664,536, May 30, 2023, "ELECTROLYTES FOR LITHIUM BATTERIES WITH CARBON AND/OR SILICON ANODES (iEdison No. 0685901-20-0027)".
- U.S. Patent No. 11,600,859, March 7, 2023, "ELECTROLYTE FOR STABLE CYCLING OF RECHARGEABLE ALKALI METAL AND ALKALI ION BATTERIES (incorporates 31452-E) (iEdison No. 0685901-18-0024)".
- U.S. Patent No. 11,127,980, September 21, 2021, "LOCALIZED SUPERCONCENTRATED ELECTROLYTES FOR SILICON ANODES".
- U.S. Patent No. 11,094,966, August 17, 2021, "HIGH EFFICIENCY ELECTROLYTES FOR HIGH VOLTAGE BATTERY SYSTEMS".
- U.S. Patent No. 10,854,923, December 1, 2020, "LOW FLAMMABILITY ELECTROLYTES FOR STABLE OPERATION OF LITHIUM AND SODIUM ION BATTERIES ".
- U.S. Patent No. 10,734,641, August 4, 2020, "HIGH CAPACITY AND STABLE CATHODE MATERIALS".
- U.S. Patent No. 10,547,088, January 28, 2020, "HIGH COULOMBIC EFFICIENCY CYCLING OF METAL BATTERIES".
- U.S. Patent No. 10,472,571, November 12, 2019, "LOW FLAMMABILITY ELECTROLYTES FOR STABLE OPERATION OF ELECTROCHEMICAL DEVICES ".
- U.S. Patent No. 10,367,189, July 30, 2019, " ANODE-FREE RECHARGEABLE BATTERY ".
- U.S. Patent No. 10,243,206, March 26, 2019, "HIGH CAPACITY AND STABLE CATHODE MATERIALS".
- U.S. Patent No. 10,170,795, January 1, 2019, "Electrolyte for high efficiency cycling of sodium metal and rechargeable sodium-based batteries comprising the electrolyte".
- U.S. Patent No. 9,184,436, November 10, 2015, "Methods and Energy Storage Devices Utilizing Electrolytes Having Surface-Smoothing Additives".
- U.S. Patent No. 9,130,218, September 8, 2015, "Hybrid Energy Storage System Utilizing Redox Active Organic Compounds ".
- U.S. Patent No. 9,115,435, August 25, 2015, "Methods for associating or dissociating guest materials with a metal organic framework, systems for associating or dissociating guest materials within a series of metal organic frameworks, and gas separation assemblies".
- U.S. Patent No. 9,039,788, May 26, 2015, "Methods for making anodes for lithium ion batteries".
- U.S. Patent No. 8,980,460, March 17, 2015, "Methods and Electrolytes for Electrodeposition of Smooth Films".
- U.S. Patent No. 8,765,278, July 1, 2014, "HIGH-ENERGY METAL AIR BATTERIES ".
- U.S. Patent No. 8,758,947, June 24, 2014, "Graphene-Based Battery Electrodes Having Continuous Flow Paths".
- U.S. Patent No. 8,450,014, May 28, 2013, "Lithium Ion Batteries with Titania/AnGraphene Anodes".
- U.S. Patent No. 8,425,662, April 23, 2013, "Methods for Associating or Dissociating Guest Materials with a Metal Organic Framework, Systems for Associating or Dissociating Guest Materials Within a Series of Metal Organic Frameworks and Gas Separation Assemblies".
PNNL Publications
2024
- Ahmed R.A., K. Koirala, G. Lee, T. Li, Q. Zhao, Y. Fu, and L. Zhong, et al. 2024. "Enhanced Electrochemical Performance of Disordered Rocksalt Cathodes in a Localized High-Concentration Electrolyte." Advanced Energy Materials 14, no. 27:Art. No. 2400722. PNNL-SA-194465. doi:10.1002/aenm.202400722
- Kim J., P. Gao, Q. Miao, Q. Zhao, M.M. Rahman, P. Chen, and X. Zhang, et al. 2024. "Tailoring solvation solvent in localized high-concentration electrolytes for lithium||sulfurized polyacrylonitrile batteries." ACS Applied Materials & Interfaces 16, no. 16:20618-20625. PNNL-SA-193968. doi:10.1021/acsami.4c02326
- Koirala K., L. Jiang, S. Patil, P. Longo, Z. Liu, B. Freitag, and J. Barthel, et al. 2024. "Direct Mapping of Fluorine in Cation Disordered Rocksalt Cathodes." ACS Energy Letters 9, no. 1:10-16. PNNL-SA-191354. doi:10.1021/acsenergylett.3c02154
- Tran T., X. Cao, Y. Xu, P. Gao, H. Zhou, F. Guo, and K. Han, et al. 2024. "Enhancing Cycling Stability of Lithium Metal Batteries by A Bifunctional Fluorinated Ether." Advanced Functional Materials 34, no. 42:2407012. PNNL-SA-197241. doi:10.1002/adfm.202407012
- Xu W. 2024. Development of Electrolytes for Lithium Ion Batteries in Low Temperature Applications - CRADA 373 (Abstract). PNNL-35402. Richland, WA: Pacific Northwest National Laboratory. Development of Electrolytes for Lithium Ion Batteries in Low Temperature Applications - CRADA 373 (Abstract)
2023
- Buyuker I., B. Pei, H. Zhou, X. Cao, Z. Yu, S. Liu, and W. Zhang, et al. 2023. "Voltage and Temperature Limits of Advanced Electrolytes for Lithium-Metal Batteries." ACS Energy Letters 8, no. 4:1735-1743. PNNL-SA-181739. doi:10.1021/acsenergylett.3c00235
- Cheng C., Y. Zhou, Y. Xu, H. Jia, J. Kim, W. Xu, and C. Wang, et al. 2023. "Dynamic Molecular Investigation of the Solid-Electrolyte Interphase of an Anode-Free Lithium Metal Battery Using In Situ Liquid SIMS and Cryo-TEM." Nano Letters 23, no. 18:8385-8391. PNNL-SA-185620. doi:10.1021/acs.nanolett.3c00709
- Corey E.M., Q. Wu, N. Gao, Y. Zhang, H. Zhu, K. Gering, and M. Hurley, et al. 2023. "Localized high-concentration electrolytes get more localized through micelle-like structures." Nature Materials 22, no. 12:1531-1539. PNNL-SA-178219. doi:10.1038/s41563-023-01700-3
- Feng G., Y. Shi, H. Jia, S. Risal, X. Yang, P. Ruchhoeft, and W. Shih, et al. 2023. "Progressive and Instantaneous Nature of Lithium Nucleation Discovered by Dynamic and Operando Imaging." Science Advances 9, no. 21:Art. No. eadg6813. PNNL-SA-178235. doi:10.1126/sciadv.adg6813
- Kautz D.J., X. Cao, P. Gao, B.E. Matthews, Y. Xu, K. Han, and F.O. Omenya, et al. 2023. "Designing Electrolytes With Controlled Solvation Structure for Fast-Charging Lithium-Ion Batteries." Advanced Energy Materials 13, no. 35:Art. No. 2301199. PNNL-SA-184367. doi:10.1002/aenm.202301199
- Lim H., W. Kwak, D. Nguyen, W. Wang, W. Xu, and J. Zhang. 2023. "Three-Dimensionally Semi-Ordered Macroporous Air Electrodes for Metal-Oxygen Batteries." Journal of Materials Chemistry A 11, no. 11:5746-5753. PNNL-SA-180310. doi:10.1039/D2TA09442H
- Werres M., Y. Xu, H. Jia, C. Wang, W. Xu, A. Latz, and B. Horstmann. 2023. "Origin of heterogeneous stripping of lithium in liquid electrolytes." ACS Nano 17, no. 11:10218-10228. PNNL-SA-179910. doi:10.1021/acsnano.3c00329
- Xu W. Development of Electrolytes for Lithium Ion Batteries in Wide Temperature Range Applications - CRADA 372 (Abstract). Development of Electrolytes for Lithium Ion Batteries in Wide Temperature Range Applications - CRADA 372 (Abstract)
- Xu W. 2023. Development of Electrolytes for Lithium Ion Batteries in Wide Temperature Range Applications - CRADA 372 (Abstract). PNNL-35403. Richland, WA: Pacific Northwest National Laboratory. Development of Electrolytes for Lithium Ion Batteries in Wide Temperature Range Applications - CRADA 372 (Abstract)
2022
- Broekhuis B.G., H. Jia, and W. Xu. 2022. Additives in Localized High Concentration Electrolytes for Safe Lithium-Ion Batteries. PNNL-33039. Richland, WA: Pacific Northwest National Laboratory. Additives in Localized High Concentration Electrolytes for Safe Lithium-Ion Batteries
- Kim J., Y. Xu, M.H. Engelhard, J. Hu, H. Lim, H. Jia, and Z. Yang, et al. 2022. "Facile Dual-Protection Layer and Advanced Electrolyte Enhancing Performances of Cobalt-Free/Nickel-Rich Cathodes in Lithium-Ion Batteries." ACS Applied Materials & Interfaces 14, no. 15:17405-17414. PNNL-SA-168201. doi:10.1021/acsami.2c01694
- Li Q., R. Yi, Y. Xu, X. Cao, C. Wang, W. Xu, and J. Zhang. 2022. "Failure analysis and design principles of silicon-based lithium-ion batteries using micron-sized porous silicon/carbon composite." Journal of Power Sources 548, no. n/a:232063. PNNL-SA-168200. doi:10.1016/j.jpowsour.2022.232063
- Xu K., W. Xu, and S. Zhang. 2022. "Austen Angell's legacy in electrolyte research." Journal of Non-Crystalline Solids: X 14. PNNL-SA-169405. doi:10.1016/j.nocx.2022.100088
- Xu W., H. Jia, L. Zhong, and X. Cao. 2022. High-Safety Electrolytes for Lithium-Ion Batteries : Is non-flammability of electrolyte overrated in the overall safety performance of lithium ion batteries?. PNNL-33366. Richland, WA: Pacific Northwest National Laboratory. High-Safety Electrolytes for Lithium-Ion Batteries : Is non-flammability of electrolyte overrated in the overall safety performance of lithium ion batteries?
- Zhang R., C. Wang, P. Zou, R. Lin, L. Ma, L. Yin, and T. Li, et al. 2022. "Compositionally complex doping for zero-strain zero-cobalt layered cathodes." Nature 610, no. 7930:67-73. PNNL-SA-170190. doi:10.1038/s41586-022-05115-z
- Zhang X., P. Gao, Z. Wu, M.H. Engelhard, X. Cao, H. Jia, and Y. Xu, et al. 2022. "Pinned Electrode/Electrolyte Interphase and Its Formation Origin for Sulfurized Polyacrylonitrile Cathode in Stable Lithium Batteries." ACS Applied Materials & Interfaces 14, no. 46:52046-52057. PNNL-SA-175354. doi:10.1021/acsami.2c16890
2021
- Cao X., H. Jia, W. Xu, and J. Zhang. 2021. "Review-Localized high-concentration electrolytes for lithium batteries." Journal of the Electrochemical Society 168, no. 1:010522. PNNL-SA-157885. doi:10.1149/1945-7111/abd60e
- Cao X., L. Zou, B.E. Matthews, L. Zhang, X. He, X. Ren, and M.H. Engelhard, et al. 2021. "Optimization of fluorinated orthoformate based electrolytes for practical high-voltage lithium metal batteries." Energy Storage Materials 34, no. n/a:76-84. PNNL-SA-153014. doi:10.1016/j.ensm.2020.08.035
- Cao X., P. Gao, X. Ren, L. Zou, M.H. Engelhard, B.E. Matthews, and J. Hu, et al. 2021. "Effects of fluorinated solvents on electrolyte solvation structures and electrode/electrolyte interphases for lithium metal batteries." Proceedings of the National Academy of Sciences (PNAS). 118, no. 9:e2020357118. PNNL-SA-154541. doi:10.1073/pnas.2020357118
- Gao P., H. Wu, X. Zhang, H. Jia, J. Kim, M.H. Engelhard, and C. Niu, et al. 2021. "Optimization of Magnesium-Doped Lithium Metal Anode for High Performance Lithium Metal Batteries through Modeling and Experiment." Angewandte Chemie International Edition 60, no. 30:16506-16513. PNNL-SA-155950. doi:10.1002/anie.202103344
- Horstmann B., J. Shi, R. Amine, M. Werres, X. He, H. Jia, and F. Hausen, et al. 2021. "Strategies towards enabling lithium metal in batteries: interphases and electrodes." Energy & Environmental Science 14, no. 10:5289-5314. PNNL-SA-160592. doi:10.1039/d1ee00767j
- Jia H., and W. Xu. 2021. "Nonflammable Nonaqueous Electrolytes for Lithium Batteries." Current Opinion in Electrochemistry 30. PNNL-SA-161413. doi:10.1016/j.coelec.2021.100781
- Jia H., X. Zhang, Y. Xu, L. Zou, J. Kim, P. Gao, and M.H. Engelhard, et al. 2021. "Toward the Practical Use of Cobalt-Free Lithium-Ion Batteries by an Advanced Ether-Based Electrolyte." ACS Applied Materials & Interfaces 13, no. 37:44339-44347. PNNL-SA-162906. doi:10.1021/acsami.1c12072
- Jia H., Y. Xu, X. Zhang, S.D. Burton, P. Gao, B.E. Matthews, and M.H. Engelhard, et al. 2021. "Advanced low-flammable electrolytes for stable operation of high-voltage lithium-ion batteries." Angewandte Chemie International Edition 60, no. 23:12999-13006. PNNL-SA-159888. doi:10.1002/anie.202102403
- Lim H., W. Kwak, S. Chae, S. Wi, L. Li, J. Hu, and J. Tao, et al. 2021. "Stable Solid Electrolyte Interphase Layer Formed by Electrochemical Pretreatment of Gel Polymer Coating on Li Metal Anode for Lithium-Oxygen Batteries." ACS Energy Letters 6, no. 9:3321-3331. PNNL-SA-162928. doi:10.1021/acsenergylett.1c01144
- Liu Y., X. Wu, C. Niu, W. Xu, X. Cao, J. Zhang, and X. Jiang, et al. 2021. "Systematic Evaluation of Carbon Hosts for High-Energy Rechargeable Lithium-Metal Batteries." ACS Energy Letters 6, no. 4:1550-1559. PNNL-SA-158156. doi:10.1021/acsenergylett.1c00186
- Niu C., D. Liu, J.A. Lochala, C.S. Anderson, X. Cao, M.E. Gross, and W. Xu, et al. 2021. "Balancing Interfacial Reactions to Achieve Long Cycle Life in High Energy Lithium Metal Batteries." Nature Energy 6, no. 7:723-732. PNNL-SA-158492. doi:10.1038/s41560-021-00852-3
- Wu H., H. Jia, C. Wang, J. Zhang, and W. Xu. 2021. "Recent progress in understanding solid electrolyte interphase on lithium metal anode." Advanced Energy Materials 11, no. 5:2003092. PNNL-SA-155507. doi:10.1002/aenm.202003092
- Wu H., P. Gao, H. Jia, L. Zou, L. Zhang, X. Cao, and M.H. Engelhard, et al. 2021. "A Polymer-in-Salt Electrolyte with Enhanced Oxidative Stability for Lithium Metal Polymer Batteries." ACS Applied Materials & Interfaces 13, no. 27:31583-31593. PNNL-SA-159667. doi:10.1021/acsami.1c04637
- Zhang J., Q. Li, X. Li, W. Xu, and R. Yi. 2021. Silicon-Based Anodes for Long-Cycle-Life Lithium-ion Batteries. PNNL-31881. Richland, WA: Pacific Northwest National Laboratory. Silicon-Based Anodes for Long-Cycle-Life Lithium-ion Batteries
- Zhang X., H. Jia, L. Zou, Y. Xu, L. Mu, Z. Yang, and M.H. Engelhard, et al. 2021. "Electrolyte Regulating toward Stabilization of Cobalt-Free Ultrahigh-Nickel Layered Oxide Cathode in Lithium-Ion Batteries." ACS Energy Letters 6, no. 4:1324-1332. PNNL-SA-158874. doi:10.1021/acsenergylett.1c00374
2020
- Jia H., Y. Xu, S.D. Burton, P. Gao, X. Zhang, B.E. Matthews, and M.H. Engelhard, et al. 2020. "Enabling Ether-Based Electrolytes for Long Cycle Life of Lithium-Ion Batteries at High Charge Voltage." ACS Applied Materials & Interfaces 12, no. 49:54893-54903. PNNL-SA-156239. doi:10.1021/acsami.0c18177
- Kwak W., S. Chae, R. Feng, P. Gao, J. Read, M.H. Engelhard, and L. Zhong, et al. 2020. "Optimized Electrolyte with High Electrochemical Stability and Oxygen Solubility for Lithium-Oxygen and Lithium-Air Batteries." ACS Energy Letters 5, no. 7:2182-2190. PNNL-SA-150369. doi:10.1021/acsenergylett.0c00809
- Malhotra D., Y. Jiang, P.K. Koech, and W. Xu. 2020. A modular chemo-selective oxygen production unit to deliver oxygen for advanced combustion systems. PNNL-30795. Richland, WA: Pacific Northwest National Laboratory. A modular chemo-selective oxygen production unit to deliver oxygen for advanced combustion systems
- Peng Z., X. Cao, P. Gao, H. Jia, X. Ren, S. Roy, and Z. Li, et al. 2020. "High-Power Lithium Metal Batteries Enabled by High-Concentration Acetonitrile-Based Electrolytes with Vinylene Carbonate Additive." Advanced Functional Materials 30, no. 24:2001285. PNNL-SA-149736. doi:10.1002/adfm.202001285
- Ren X., P. Gao, L. Zou, S. Jiao, X. Cao, X. Zhang, and H. Jia, et al. 2020. "Role of inner solvation sheath within salt-solvent complexes in tailoring electrode/electrolyte interphases for lithium metal batteries." Proceedings of the National Academy of Sciences (PNAS) 117, no. 46:28603-28613. PNNL-SA-153382. doi:10.1073/pnas.2010852117
- Ren X., X. Zhang, Z. Shadike, L. Zou, H. Jia, X. Cao, and M.H. Engelhard, et al. 2020. "Designing Advanced In Situ Electrode/Electrolyte Interphases for Wide Temperature Operation of 4.5 V Li || LiCoO2 Batteries." Advanced Materials 32, no. 49:2004898. PNNL-SA-154434. doi:10.1002/adma.202004898
- Wang H., X. Cao, H. Gu, Y. Liu, Y. Li, Z. Zhang, and W. Huang, et al. 2020. "Improving Lithium Metal Composite Anodes with Seeding and Pillaring Effects of Silicon Nanoparticles." ACS Nano 14, no. 4:4601-4608. PNNL-SA-150465. doi:10.1021/acsnano.0c00184
- Wang H., Y. Shao, H. Pan, X. Feng, Y. Chen, Y. Liu, and E.D. Walter, et al. 2020. "A lithium-sulfur battery with a solution-mediated pathway operating under lean electrolyte conditions." Nano Energy 76, no. n/a:105041. PNNL-SA-143093. doi:10.1016/j.nanoen.2020.105041
- Xu Y., H. Wu, H. Jia, M.H. Engelhard, J. Zhang, W. Xu, and C. Wang. 2020. "Sweeping potential regulated structural and chemical evolution of solid-electrolyte interphase on Cu and Li as revealed by cryo-TEM." Nano Energy 76, no. n/a:105040. PNNL-SA-153402. doi:10.1016/j.nanoen.2020.105040
- Xu Y., H. Wu, Y. He, Q. Chen, J. Zhang, W. Xu, and C. Wang. 2020. "Atomic to Nanoscale Origin of Vinylene Carbonate Enhanced Cycling Stability of Lithium Metal Anode Revealed by Cryo-Transmission Electron Microscopy." Nano Letters 20, no. 1:418-425. PNNL-SA-149594. doi:10.1021/acs.nanolett.9b04111
- Zhang J., W. Xu, J. Xiao, X. Cao, and J. Liu. 2020. "Lithium Metal Anodes with Nonaqueous Electrolytes." Chemical Reviews 120, no. 24:13312-13348. PNNL-SA-142974. doi:10.1021/acs.chemrev.0c00275
- Zhang X., H. Jia, Y. Xu, L. Zou, M.H. Engelhard, B.E. Matthews, and C. Wang, et al. 2020. "Unravelling high-temperature stability of lithium-ion battery with lithium-rich oxide cathode in localized high-concentration electrolyte." Journal of Power Sources Advances 5, no. n/a:100024. PNNL-SA-152836. doi:10.1016/j.powera.2020.100024
- Zhang X., L. Zou, Y. Xu, X. Cao, M.H. Engelhard, B.E. Matthews, and L. Zhong, et al. 2020. "Advanced electrolytes for fast-charging high-voltage lithium-ion batteries in wide-temperature range." Advanced Energy Materials 10, no. 22:2000368. PNNL-SA-150274. doi:10.1002/aenm.202000368
- Zhao W., L. Zou, H. Jia, J. Zheng, d. wang, J. Song, and C. Hong, et al. 2020. "Optimized Al Doping Improves Both Interphase Stability and Bulk Structural Integrity of Ni-Rich NMC Cathode Materials." ACS Applied Energy Materials 3, no. 4:3369-3377. PNNL-SA-144184. doi:10.1021/acsaem.9b02372
- Zhou Y., M. Su, X. Yu, Y. Zhang, J. Wang, X. Ren, and R. Cao, et al. 2020. "Real-time mass spectrometric characterization of the solid-electrolyte interphase of a lithium-ion battery." Nature Nanotechnology 15, no. 3:224-230. PNNL-SA-144845. doi:10.1038/s41565-019-0618-4
2019
- Cao X., X. Ren, L. Zou, M.H. Engelhard, W. Huang, H. Wang, and B.E. Matthews, et al. 2019. "Monolithic solid-electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization." Nature Energy 4, no. 9:796-805. PNNL-SA-141828. doi:10.1038/s41560-019-0464-5
- Cao X., Y. Xu, L. Zhang, M.H. Engelhard, L. Zhong, X. Ren, and H. Jia, et al. 2019. "Nonflammable Electrolytes for Lithium Ion Batteries Enabled by Ultraconformal Passivation Interphases." ACS Energy Letters 4, no. 10:2529-2534. PNNL-SA-145269. doi:10.1021/acsenergylett.9b01926
- Chen S., C. Niu, H. Lee, Q. Li, L. Yu, W. Xu, and J. Zhang, et al. 2019. "Critical Parameters for Evaluating Coin Cells and Pouch Cells of Rechargeable Li-Metal Batteries." Joule 3, no. 4:1094-1105. PNNL-SA-131547. doi:10.1016/j.joule.2019.02.004
- He Y., X. Ren, Y. Xu, M.H. Engelhard, X. Li, J. Xiao, and J. Liu, et al. 2019. "Origin of Lithium Whisker Formation and Growth under Stress." Nature Nanotechnology 14, no. 11:1042-1047. PNNL-SA-144887. doi:10.1038/s41565-019-0558-z
- Jia H., L. Zou, P. Gao, X. Cao, W. Zhao, Y. He, and M.H. Engelhard, et al. 2019. "High-performance silicon anodes enabled by nonflammable localized high-concentration electrolytes." Advanced Energy Materials 9, no. 31:Article No. 1900784. PNNL-SA-141600. doi:10.1002/aenm.201900784
- Liu B., Q. Li, M.H. Engelhard, Y. He, X. Zhang, D. Mei, and C. Wang, et al. 2019. "Constructing Robust Electrode/Electrolyte Interphases to Enable Wide Temperature Applications of Lithium-Ion Batteries." ACS Applied Materials & Interfaces 11, no. 24:21496-21505. PNNL-SA-141223. doi:10.1021/acsami.9b03821
- Liu J., Z. Bao, Y. Cui, E. Dufek, J. Goodenough, P. Khalifah, and Q. Li, et al. 2019. "Pathways for Practical High-Energy Long-Cycling Lithium Metal Batteries." Nature Energy 4, no. 3:180-186. PNNL-SA-129839. doi:10.1038/s41560-019-0338-x
- Niu C., H. Lee, S. Chen, Q. Li, J. Du, W. Xu, and J. Zhang, et al. 2019. "High-energy lithium metal pouch cells with limited anode swelling and long stable cycles." Nature Energy 4, no. 7:551-559. PNNL-SA-139913. doi:10.1038/s41560-019-0390-6
- Niu C., H. Pan, W. Xu, J. Xiao, J. Zhang, L. Luo, and C. Wang, et al. 2019. "Self-Smoothing Anode for Achieving High-Energy Lithium Metal Batteries under Realistic Conditions." Nature Nanotechnology 14, no. 6:594-601. PNNL-SA-135477. doi:10.1038/s41565-019-0427-9
- Peng Z., F. Ren, S. Yang, M. Wang, J. Sun, D. Wang, and W. Xu, et al. 2019. "A Highly stable host for lithium metal anode enabled by Li9Al4-Li3N-AlN structure." Nano Energy 59. PNNL-SA-139672. doi:10.1016/j.nanoen.2019.02.033
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2018
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2017
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2016
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2015
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2014
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2013
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2012
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2011
- Choi D., J. Xiao, Y. Choi, J.S. Hardy, M. Vijayakumar, M.S. Bhuvaneswari, and J. Liu, et al. 2011. "Thermal Stability and Phase Transformation of Electrochemically Charged/Discharged LiMnPO4 Cathode for Li-Ion Battery." Energy & Environmental Science 4, no. 11:4560-4566. PNNL-SA-79713. doi:10.1039/C1EE01501J
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2010
- Huang J.Y., L. Zhong, C.M. Wang, J.P. Sullivan, W. Xu, L.Q. Zhang, and S. Mao, et al. 2010. "In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode." Science 330, no. 6010:1515-1520. PNNL-SA-75254. doi:10.1126/science.1195628
- Pan A., J. Liu, J. Zhang, G.H. Cao, W. Xu, Z. Nie, and J. Xiao, et al. 2010. "Template Free Synthesis of LiV3O8 Nanorods as a Cathode Material for High-Rate Secondary Lithium Batteries." Journal of Materials Chemistry 21, no. 4:1153-1161. PNNL-SA-73809. doi:10.1039/c0jm02810j
- Pan A., J. Liu, J. Zhang, W. Xu, G.H. Cao, Z. Nie, and B.W. Arey, et al. 2010. "Nano-Structured Li3V2(PO4)3 /Carbon Composite for High Rate Lithium Ion Batteries." Electrochemistry Communications 12, no. 12:1674-1677. PNNL-SA-73952. doi:10.1016/j.elecom.2010.09.014
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- Xiao J., D. Wang, W. Xu, D. Wang, R.E. Williford, J. Liu, and J. Zhang. 2010. "Optimization of Air Electrode for Li/Air Batteries." Journal of the Electrochemical Society 157, no. 4:A487-A492. PNNL-SA-68745. doi:10.1149/1.3314375
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2009
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- Xu W., J. Xiao, J. Zhang, D. Wang, and J. Zhang. 2009. "Optimization of non-aqueous electrolytes for Primary lithium/air batteries operated in Ambient Enviroment." Journal of the Electrochemical Society 156, no. 10:A773-A779. PNNL-SA-66402. doi:10.1149/1.3168564